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Item Chemical abundances in Seyfert galaxies – X. Sulphur abundance estimates(Royal Astronomical Society) Dors Junior, Oli Luiz; Valerdi, Mabel; Riffel, Rogemar André; Riffel, Rogério; Cardaci, Mónica Viviana; Hägele, Guilhermo Frederico; Armah, Mark; Revalski, Mitchell; Flury, Sophia; Lemes, Priscila Freitas; Amôres, Eduardo; Krabbe, Angela Cristina; Binette, Luc; Feltre, Anna; Bergmann, Thaisa StorchiFor the first time, the sulphur abundance relative to hydrogen (S/H) in the narrow-line regions of a sample of Seyfert 2 nuclei (Sy 2s) has been derived via direct estimation of the electron temperature. Narrow emission-line intensities from the Sloan Digital Sky Survey (SDSS) Data Release 17 (DR17) [in the wavelength range 3000 < λ(Å) < 9100] and from the literature for a sample of 45 nearby (z < 0.08) Sy 2s were considered. Our direct estimates indicate that Sy 2s have similar temperatures in the gas region where most of the S+ ions are located in comparison with that of star-forming regions (SFs). However, Sy 2s present higher temperature values (∼10 000 K) in the region where most of the S2+ ions are located relative to that of SFs. We derive the total sulphur abundance in the range of 6.2 12 + log(S/H) 7.5, corresponding to 0.1–1.8 times the solar value. These sulphur abundance values are lower by ∼0.4 dex than those derived in SFs with similar metallicity, indicating a distinct chemical enrichment of the interstellar medium (ISM) for these object classes. The sulphur abundance relative to oxygen (S/O) values for our Sy 2 sample present an abrupt (∼0.5 dex) decrease with increasing oxygen abundance relative to hydrogen (O/H) for the high-metallicity regime [12 + log(O/H) 8.7)], what is not seen for the SFs. However, when our Sy 2 estimates are combined with those from a large sample of SFs, we did not find any dependence between S/O and O/H.Item Chemical abundances of LINER galaxies – nitrogen abundance estimations(Royal Astronomical Society) Oliveira Junior, Celso Benedito de ; Krabbe, Angela Cristina; Dors Junior, Oli Luiz; Zinchenko, Igor; Hernandez-Jimenez, José Andrés; Cardaci, Mónica Viviana; Hägele, Guilhermo Frederico; Ilha, Gabriele da SilvaIn this work, we investigated the nitrogen and oxygen abundances in a sample of galaxies with Low Ionization Nuclear Emission Regions (LINERs) in their nucleus. Optical spectroscopic data (3600 – 10 000 Å) of 40 LINERs from the Mapping Nearby Galaxies (MaNGAs) survey were considered. Only objects classified as retired galaxies, that is, whose main ionization sources are post-Asymptotic Giant Branch (pAGB) stars, were selected. The abundance estimates were obtained through detailed photoionization models built with the CLOUDY code to reproduce a set of observational emission line intensities ratios of the sample. Our results show that LINERs have oxygen and nitrogen abundances in the ranges of 8.0 12 + log(O/H) 9.0 (mean value 8.74 ± 0.27) and 7.6 12 + log(N/H) 8.5 (mean value 8.05 ± 0.25), respectively. About 70 per cent of the sample have oversolar O/H and N/H abundances. Our abundance estimates are in consonance with those for Seyfert 2 nuclei and H II regions with the highest metallicity, indicating that these distinct object classes show similar enrichment of the interstellar medium (ISM). The LINERs in our sample are located in the higher N/O region of the N/O versus O/H diagram, showing an unexpected negative correlation between these two parameters. These results suggest that these LINERs mainly exhibit a secondary nitrogen production and could be acting some other mechanisms that deviate them from the usual theoretical secondary nitrogen production curve and the H II regions observations. However, we did not find any evidence in our data able to support the literature suggested mechanisms. Alternatively, our results show that LINERs do not present any correlation between the N/O abundances and the stellar masses of the hosting galaxies.Item Metallicity of active galactic nuclei from ultraviolet and optical emission lines: I. Carbon abundance dependence(Royal Astronomical Society) Dors Junior, Oli Luiz; Oliveira Junior, Celso Benedito de; Cardaci, Mónica Viviana; Hagele, Guillermo Federico; Morais, Istenio Nunes de; Ji, Xihan; Riffel, Rogemar André; Riffel, Rogério; Mezcua, Mar; Almeida, Gleicy Caroline de; Santos, Pedro Camargo; Mellos, Maitê Silvana de Zorzi deMetallicity (Z) estimates based on ultraviolet (UV) emission lines from the narrow-line regions of active galactic nuclei (AGNs) have been found to differ from those derived from optical lines. However, the origin of this discrepancy (ZR) remains poorly understood. To investigate the source of ZR, we compiled from the literature the fluxes of narrow near- UV [1000 < λ(Å) < 2000] and optical [3000 < λ(Å) < 7000] emission-line measurements for a sample of 11 AGNs (nine at z < 0.4 and two at z ∼ 2.4). Metallicity values for our sample were derived using a semi-empirical calibration based on the C43 = log[(C IVλ1549 + C III]λ1909)/He IIλ1640] emission-line ratio and compared with those obtained via direct measurement of the electron temperature (Te-method) and via calibrations based on optical emission lines. The source of the discrepancy was investigated in terms of the ionization parameter (U), electron density (Ne), and carbon abundance (C/H). We found a weak correlation between ZR, U, and Ne. However, a moderate correlation was observed between ZR and direct estimates of C/H, suggesting that the previously assumed (C/O)–Z relations in photoionization models used to derive UV carbon-line calibrations may not be valid for AGNs. By combining a large set of abundance estimates for local star-forming regions with those of our AGN sample, we derived a new (C/O)–Z relation. Comparisons between the results of photoionization models that assume this new abundance relation and the UV observational data of our sample produce Z values derived from the C43 index that are consistent with those obtained using the Te-method.