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Evidence of anti-correlation between sporadic (Es) layers occurrence and solar activity observed at low latitudes over the Brazilian sector
(Elsevier) Fontes Neto, Pedro Alves; Muella, Marcio Tadeu de Assis Honorato; Resende, Laysa Cristina Araújo; Fagundes, Paulo Roberto
Sporadic E-layers (Es) are thin and denser layers with high ionization observed at about 100–140 km altitude in the E region. Their formation is mainly associated with the tidal components of the diurnal and semidiurnal winds with the convergence of ions driven by the wind shear mechanism. This present work shows evidence of the relationship between the occurrence of Es layers and the solar activity at two observatories located in the Brazilian sector, the near-equatorial site of Palmas (PAL, 10.17 S; 48.33 W; dip lat. 7.31 ) and the low latitude station of Sa ̃o Jose ́ dos Campos (SJC, 23.18 S; 45.89 W; dip lat. 19.35 ). The analysis was performed from Decem- ber/2008 to November/2009 (a period of low solar activity) and from December/2013 to November/2014 (a period of high solar activity) using data collected from two digital ionosondes. Our results show an anti-correlation of the Es layer occurrence concerning the solar activity over both stations studied here. A more clearly observed anti-correlation at the SJC station can be attributed to a greater tidal amplitude at low latitudes. Other relevant aspects of the observations associated with the formation of the Es layers are highlighted and discussed.
Exploring patterns in dendrochronological data through cluster analysis
(Universidade Federal do Paraná) Muraja, Daniela Oliveira Silva; Leite, Cecília Lemes; Klausner, Virginia; Prestes, Alan; Silva, Iuri Rojahn da
This study employed the dendrogram methodology to analyze time series data obtained from measuring tree growth rings. A total of 64 samples were collected from 21 individual trees. Polynomials were applied to filter the natural growth pattern of the trees and enhance the impact of external factors, such as climate influences. Cluster analysis using Ward's minimum variance and Euclidean squared distance was utilized to group the data based on similarity. Three dendrograms were constructed, consisting of 10, 47, and 64 samples, respectively. The analysis revealed that the samples with the highest correlations, encompassing over 95% of the total samples, formed homogeneous groups. Pearson correlation was also employed to confirm the results obtained from the dendrograms. Consequently, it can be affirmed that the most suitable samples were utilized in constructing the average chronology from the available data.
Lithosphere atmosphere ionosphere coupling during the September 2015 Coquimbo earthquake
(Springer Nature Link) Adhikari, Bhoj Raj; Klausner, Virgínia; Cândido, Claudia Maria Nicoli; Poudel, Prakash; Macedo, Humberto Gimenes; Silwal, Ashok; Gautam, Sujan Prasad; Calabia, Andrés; Shah, Munawar
This study explores temporal variations in seismic data, interplanetary parameters, and geomagnetic indices during the 2015 Coquimbo earthquake. We employ wavelet transform techniques to investigate potential coupling mechanisms between the lithosphere, atmosphere, and ionosphere (LAI), even during geomagnetically disturbed periods. Our analysis is strengthened by evaluating geomagnetic data and all- sky images within a 2000–3000 km radius of the epicenter. We explore the post-Chilean earthquake seismogenic perturbations in the upper atmosphere on September 16–17, 2015. Coseismic and post- seismic events emerge in the Brazilian region 1–3 hrs after the earthquake onset. The co-occurrence and subsequent response of these disturbances to seismic events suggest their seismogenic nature. Addi- tionally, we utilize geomagnetic storm and interplanetary magnetic Beld (IMF) indices to differentiate magnetic Cuctuations arising from solar storms during seismic events. While our study detects magnetic disturbances associated with seismic activity, distinguishing them from the eAects of solar storms in the geomagnetic records or all-sky images remains challenging. These observations prompt further investigation into the intricate interplay between geomagnetic and ionospheric disturbances and their connection to seismic and geomagnetic storm activity.
Modeling the chemical evolution and kinetics of pure H2O Ices under various types of radiation employing the PROCODA code
(Elsevier) Silveira, Carolina Hahn da; Pilling, Sergio
Water is one of the most abundant molecules in space, especially in cold environments, where it is the main constituting of astrophysical ices. The space ionizing radiation affects these ices and induces chemical changes, including desorption to gas-phase, which increase the complexity of the interstellar medium. In this work, we employed the PROCODA code to investigate the behavior of several pure water ices under different type of ionizing radiation such as UV, X-rays, electrons and cosmic rays analogues. Here, we employ molecular column densities from laboratory and solved a set of coupled chemical reactions to calculated effective reaction rates (ERCs) and characterize the chemical equilibrium of water ices under high radiation fluences. Briefly, we monitored the evolution of nine species (including the observed ones H2O, H2O2, and O3, and the predicted ones H, O, H2, OH, O2, and HO2). A discussion on the branching ratio for the considered reactions with the type of ionizing radiation is provided. Among the results, we observed that approximately 63% of the modeled molecules quantified at chemical equilibrium were non-observed species in the X-rays experiment, highlighting the importance of this work in providing insights into the processes that occur on the surface of icy interstellar grains exposed to cosmic radiation, including the formation and destruction of water ice. Accurate modeling of these processes can lead to a better understanding of the chemical evolution of interstellar and circumstellar environments, as well as offer insight into the formation and composition of celestial objects such as comets.
Deuteration of molecular clumps induced by cosmic rays
(Elsevier) Pilling, Sergio; Pazianotto, Maurício Tizziani; Molina, Jose Manuel Quesada
The D/H ratio in astrophysical environments has instigated the scientists for at least 50 years. The wide range of values in the interstellar medium (ISM) from 10e to 7 to 10e-1 have usually been claimed to be due to small zero-point energy differences between reactants and products involving D and H (mainly at low temperatures). Here, we present a new source of deuteration processes in the ISM clouds as a result of cosmic ray irradiation. As a study object, we consider a typical molecular clump under the presence of incoming cosmic rays simulated computationally. The calculations were performed employing the Monte Carlo toolkit GEANT4 code (considering hadronic physics) and considering mainly the proton and alpha component of the incoming cosmic rays from the ISM (the dominant ones for the production of secondary protons and deuterons). The results suggest an increasing D/H ratio as function of time in the central part of molecular clumps (<200 AU) with the largest deuteration in the central region of the cloud, and a bump in the D/H ratio around 2–10 AU (which becomes more pronounced for clouds with larger timescales; > 10 Myrs). The results also show that for timescales between 10 and 100 Myrs the central part of the cloud has D/H around 6-16e-3, a value compatible with the observed D/H in some interstellar clouds. This work adds a new piece to the D/H puzzle of the ISM and might also help to explain the D/H ratio measured in different objects inside the Solar system.
Understanding the astrophysical-ice nanostructures formation through classical molecular dynamics
(Universidade do Vale do Paraíba) Silva, Priscila Alves da; Pilling, Sergio; Amarim, Rodrigo Garcia
Astrophysical ices (formed by water, among other molecules) act as a catalyst and a reservoir of carbonaceous species, both of which have major implications for astrobiology. In this work, we studied the formation of astrophysical ice nanostructures found in the interstellar medium, having a sheet of graphene as a catalyst substrate, using the classical molecular dynamics technique to model these astrophysical environments. For this, two systems were designed: the first composed of graphene and H2Oand the second composed of graphene, H2Oand CO2. Initially, a simulation box was built where the area was delimited by graphene whose height varied from 4, 6, 8 and 10 nm. The molecules were evenly distributed throughout the box. The molecular dynamics technique proved to be a promising tool to understand the phenomenon of adsorption of molecules on the substrate, allowing us to realize that the random distribution of molecules in the system interferes with the geometric structure formed by an ice nanostructure. This study allows us to understand, from the nanometric point of view, the influence of some physical-chemical parameters, regarding the formation of nanostructures of astrophysical ices, such as the number of hydrogen bonds, the initial size of the simulation box, and its density during the freezing process
Ionospheric storm due to solar Coronal mass ejection in September 2017 over the Brazilian and African longitudes
(Elsevier) Fagundes, Paulo Roberto; Tsali-Brown, Vera Yesutor; Pillat, Valdir Gil; Arcanjo, Mateus de Oliveira; Venkatesh, Kavutarapu; Habarulema, John Bosco; Bolzan, Maurício José Alves; Jesusm Rodolfo F. de; Abreu, Alessandro José de; Tardelli, Alexandre; Vieira, Francisco; Denardini, Clezio Marcos
Coronal mass ejection (CME) occurs when there is an abrupt release of a large amount of solar plasma, and this cloud of plasma released by the Sun has an intrinsic magnetic field. In addition, CMEs often follow solar flares (SF). The CME cloud travels outward from the Sun to the interplanetary medium and eventually hits the Earth’s system. One of the most significant aspects of space weather is the ionospheric response due to SF or CME. The direction of the interplanetary magnetic field, solar wind speed, and the number of particles are relevant parameters of the CME when it hits the Earth’s system. A geomagnetic storm is most geo-efficient when the plasma cloud has an interplanetary magnetic field southward and it is accompanied by an increase in the solar wind speed and particle number density. We investigated the ionospheric response (F-region) in the Brazilian and African sectors during a geomagnetic storm event on September 07–10, 2017, using magnetometer and GPS-TEC networks data. Positive ionospheric disturbances are observed in the VTEC during the disturbed period (September 07–08, 2017) over the Brazilian and African sectors. Also, two latitudinal chains of GPS-TEC stations from the equatorial region to low latitudes in the East and West Brazilian sectors and another chain in the East African sector are used to investigate the storm time behavior of the equatorial ionization anomaly (EIA). We noted that the EIA was disturbed in the American and African sectors during the main phase of the geomagnetic storm. Also, the Brazilian sector was more disturbed than the African sector.
Diagnostic diagrams for ram pressure stripped candidates
(Royal Astronomical Society) Krabbe, Angela Cristina; Hernandez-Jimenez, José Andrés; Oliveira, Claudia Mendes de; Jaffe, Yara L.; Oliveira Junior, Celso Benedito de; Cardoso, Nathalia Machado; Castelli, Analía V Smith; Dors Junior, Oli Luiz; Cortesi, Arianna; Crossett, Jacob P.
This paper presents a method for finding ram pressure stripped (RPS) galaxy candidates by performing a morphological analysis of galaxy images obtained from the Legacy survey. We consider a sample of about 600 galaxies located in different environments such as groups and clusters, tidally interacting pairs and the field. The sample includes 160 RPS previously classified in the literature into classes from J1 to J5, based on the increasing level of disturbances. Our morphological analysis was done using the ASTROMORPHLIB software followed by the inspection of diagnostic diagrams involving combinations of different parameters like the asymmetry (A), concentration (C), Sersic ´ index (n), and bulge strength parameters F(G, M20). We found that some of those diagrams display a distinct region in which galaxies classified as J3, J4, and J5 decouples from isolated galaxies. We call this region as the morphological transition zone and we also found that tidally interacting galaxies in pairs are predominant within this zone. Nevertheless, after visually inspecting the objects in the morphological transition zone to discard obvious contaminants, we ended up with 33 bona fide new RPS candidates in the studied nearby groups and clusters (Hydra, Fornax, and CLoGS sample), of which one-third show clear evidence of unwinding arms. Future works may potentially further increase significantly the samples of known RPS using such method.
Understanding the Molecular Kinetics and Chemical Equilibrium Phase of Frozen CO during Bombardment by Cosmic Rays by Employing the PROCODA Code
(IOP science) Pilling, Sergio; Carvalho, Geanderson Araújo; Abreu, Heitor Avelino de; Galvão, Breno Rodrigues Lamaghere; Silveira, Carolina Hahn da; Mateus, Marcelo Silva
Within the cold regions of space, ices that are enriched with carbon monoxide (CO) molecules are exposed to ionizing radiation, which triggers new reactions and desorption processes. Laboratory studies on astrochemical ices employing different projectiles have revealed the appearance of several new species. In this study, we employed the upgraded PROCODA code, which involves a calculation phase utilizing thermochemistry data, to map the chemical evolution of pure CO ice irradiated by cosmic-ray analogs. In the model, we have considered 18 different chemical species (six observed: CO, CO2, C3, O3, C2O, and C5O3; 12 unobserved: C, O, C2, O2, CO3, C3O, C4O, C5O, C2O2, C2O3, C3O2, and C4O2) coupled at 156 reaction routes. Our best-fit model provides effective reaction rates (effective rate constants, (ERCs)), branching ratios for reactions within reaction groups, several desorption parameters, and the characterization of molecular abundances at the chemical equilibrium (CE) phase. The most abundant species within the ice at the CE phase were atomic oxygen (68.2%) and atomic carbon (18.2%), followed by CO (11.8%) and CO2 (1.6%). The averaged modeled desorption yield and rate were 1.3e5 molecules ion−1 and 7.4e13 molecules s−1, respectively, while the average value of ERCs in the radiation-induced dissociation reactions was 2.4e-1 s−1 and for the bimolecular reactions it was 4.4e-24 cm3 molecule−1 s−1. We believe that the current kinetics study can be used in future astrochemical models to better understand the chemical evolution of embedded species within astrophysical ices under the presence of an ionizing radiation field.
Effects of the terdiurnal tide on the sporadic E (Es) layer development at low latitudes over the Brazilian sector
(European Geosciences Union) Fontes, Pedro Alves; Muella, Marcio Tadeu de Assis Honorato; Resende, Laysa Cristina Araújo; Andrioli, Vânia Fátima; Fagundes, Paulo Roberto; Pillat, Valdir Gil; Batista, Paulo Prado; Carrasco, Alexander Jose
Sporadic E (Es) layers are patches of high ionization observed at around 100–140 km height in the E region. Their formation at low latitudes is primarily associated with the diurnal and semidiurnal components of the tidal winds via the ion convergence driven by the wind shear mechanism. However, recent studies have shown the influence of other tidal modes, such as the terdiurnal tide. Therefore, this work investigates the effect of terdiurnal tide-like oscillations on the occurrence and formation of the Es layers observed over Palmas (10.17∘ S, 48.33∘ W; dip lat. −7.31∘), a low-latitude station in Brazil. The analysis was conducted from December 2008 to November 2009 by using data collected from CADI (Canadian Advanced Digital Ionosonde). Additionally, the E Region Ionospheric Model (MIRE) was used to simulate the terdiurnal tidal component in the Es layer development. The results show modulations of 8 h periods on the occurrence rates of the Es layers during all seasonal periods. In general, we see three well-defined peaks in a superimposed summation of the Es layer types per hour in summer and autumn. We also observed that the amplitude modulation of the terdiurnal tide on the Es occurrence rates minimizes in December in comparison to the other months of the summer season. Other relevant aspects of the observations, with complementary statistical and periodogram analysis, are highlighted and discussed.
Chemical evolution of electron-bombarded crystalline water ices at different temperatures using the procoda code
(Royal Astronomical Society) Pilling, Sergio; Silveira, Carolina Hahn da; Ojeda González, Arian
Water ices are a common component of cold space environments, including molecular and protostellar clouds, and the frozen surfaces of moons, planets, and comets. When exposed to ionizing and/or thermal processing, they become a nursery for new molecular species and are also responsible for their desorption to the gas-phase. Crystalline water ice, produced by the deposition of gaseous water at warm (80–150 K) surfaces or by the heating of cold amorphous water ice (up to ∼150 K), is also regularly detected by astronomical observations. Here, we employed the procoda code to map the chemical evolution of 5 keV electron-bombarded crystalline water-ices at different temperatures (12, 40, 60 and 90 K). The chemical network considered a total of 61 coupled reactions involving nine different chemical species within the ice. Among the results, we observe that the average calculated effective rate constants for radiation-induced dissociation decrease as the ice´s temperature increases. The abundance of molecular species in the ice at chemical equilibrium and its desorption to gas-phase depend on both the temperature of the ice. H2O molecules are the dominant desorbed species, with a desorption yield of about 1 molecule per 100 electrons, which seems to be enhanced for warmer crystalline ices. The obtained results can be employed in astrochemical models to simulate the chemical evolution of interstellar and planetary environments. These findings have implications for astrochemistry and astrobiology, providing insight into crucial chemical processes and helping us understand the chemistry in cold regions in space.
Effects of the Northern Hemisphere sudden stratospheric warmings on the Sporadic-E layers in the Brazilian sector
(Elsevier) Fontes Neto, Pedro Alves; Muella, Marcio Tadeu de Assis Honorato ; Resende, Laysa Cristina Araújo; Jesus, Rodolfo de; Fagundes, Paulo Roberto; Batista, Paulo Prado; Pillat, Valdir Gil; Tardelli, Alexandre; Andrioli, Vania F.
Tidal and Planetary Wave (PWs) amplitudes are strongly influenced by Sudden Stratospheric Warming (SSW) events. A nonlinear interaction between the tidal winds and planetary waves during the SSW may contribute to the intensification of sporadic-E (Es) layers in the lower thermosphere. This work investigated the relationship between SSW events in the Northern Hemisphere and the Es layer occurrence at low latitudes in the Brazilian sector. We used data from digital ionosondes installed in the observatories of Araguatins (ARA, 5.65◦ S; 48.12◦ W; dip lat. − 5.44◦) and S ̃ao Jos ́e dos Campos (SJC, 23.18◦ S; 45.89◦ W; dip lat. − 21.37◦) to analyze the Es layers. Additionally, we used the temperature, zonal wind, and PWs data at high latitudes in the Northern Hemisphere during the major SSW event that occurred in February/2018 and during the events of Dec/2018–Jan/2019 and Dec/2020–Jan/2021. The results showed a maximum frequency peak of 20 MHz (~5 × 106 electrons.cm− 3) at ARA and SJC during these SSW events. The large values of ftEs, fbEs, and electronic densities were observed between 100 and 115 km height in the Esf/l type layers during daytime or nighttime periods. The results also showed that the number of large values of ftEs, fbEs, and electronic density of the Es layer was much higher in ARA than in SJC, in general. The wavelet power spectrum analyses of the ftEs and fbEs showed a periodicity of 2- days before and after the central day of the SSWs events at the station of ARA, with three prominent peaks in the 2018/2019 event. At the SJC station the quasi-2-day periodicity in the wavelet analyses of the ftEs was observed after the central day in all three SSW events, with a peak before the central day during the 2020/2021 event.
Enhancing learning of the Grad-Shafranov Equation through scientific literature: part 1 of a physics education series
(Sociedade Brasileira de Física) Ojeda González, Arian; Santos, Lenadro Nunes dos; La Luz, Victor Hugo de; Oliveira, Matheus Felipe Cristaldo de; Sousa, Antonio Nilson Laurindo; Prestes, Alan; Klausner, Virgínia; Pilling, Sergio
This article provides a comprehensive review of relevant studies in the fields of plasma physics, electromagnetism, and space physics. The aim is to demonstrate how the study of the scientific literature can be used to enhance problem-solving abilities and develop innovative solutions in physics. In this paper, we focus on the study of solutions of the specific Grad-Shafranov equation. Two of the new solutions proposed by Yoon and Lui (2005) are used as a basis for the development of a new solution. The new solution presented has singular points similar to the Yoon-Lui-2 solution, but with an inverted configuration, and also presents less rounded double islands compared to the Yoon-Lui-2 solution. Additionally, the new solution does not exhibit the formation of a current ring, a characteristic of the Yoon-Lui-1 solution, and varying its parameters may lead to higher plasma confinement efficiency. In summary, we illustrate how a thorough analysis of literature can serve as a powerful means for generating innovative approaches to resolving theoretical issues in physics.
Influence of temperature on the chemical evolution and desorption of pure CO ices irradiated by cosmic-rays analogues
(Royal Astronomical Society) Pilling, Sergio; Mateus, Marcelo Silva; Ojeda González, Arian; Ferrão, Luiz Fernando de Araujo; Galvão, Breno R. L.; Boduch, Philippe; Rothard, Hermann
Carbon monoxide (CO) plays a vital role in interstellar chemistry, existing abundantly in both gaseous and frozen environments. Understanding the radiation-driven chemistry of CO-rich ices is crucial for comprehending the formation and desorption of C-bearing molecules in the interstellar medium (ISM), particularly considering the potential impact of temperature on these processes. We report experimental data on irradiation processing of pure CO ice by cosmic ray analogues (95.2 MeV 136Xe23+ ions) at temperatures of 10, 15, and 20 K, in the IGLIAS set-up coupled to the IRRSUD beamline at GANIL (Caen, France). The evolution of the irradiated frozen samples was monitored by infrared spectroscopy. The computational PROCODA code allows us to quantify the chemical evolution of the samples, determining effective reaction rates coefficients (ERCs), molecular abundances at the chemical equilibrium (CE) phase, and desorption processes. The model integrated 18 chemical species – 8 observed (CO, CO2, C3, O3, C2O, C3O, C3O2, and C5O3) and 10 non-observed but predicted (C, O, C2, O2, CO3, C4O, C5O, C2O2, C2O3, C4O2) – linked via 156 reactions. Our findings reveal temperature-driven influences on molecular abundances at chemical equilibrium, desorption yields and rates, and ERC values. Certain reaction routes exhibit distinct thermochemical behaviours of gas- and ice-phase reactions which may be attributed to the presence of neighbouring molecules within the ice matrix. This study provides pivotal insights into the chemical evolution of CO-enriched ice under irradiation, impacting solid-state astrochemistry, clarifying molecular abundances, and advancing our understanding of ISM chemistry and temperature effects on ionized radiation-processed frozen ices.
Freya: an educational MATLAB GUI-based tool for generalized Fourier series
(Research, Society and Development) Macedo, Humberto Gimenes; Oliveira, Virgínia Klausner de; Gomes, Anna Karina Fontes; Fernandes, Francisco Carlos Rocha
The Fourier analysis is a very powerful mathematical tool to decompose functions into their frequency components. Due to this, it has applications in a wide variety of fields inside the realm of science and engineering. As usual, this theory starts with a discussion about the trigonometric Fourier series, the expansion of a function in terms of sines and cosines, and then is generalized in the sense that other functions rather than the trigonometric ones can be used as an orthogonal basis, as the eigenfunctions of some specific Sturm-Liouville problems, such as Bessel functions and Legendre polynomials. In this direction, we present the so- called Freya, an educational graphical user interface (GUI) for the generalized Fourier series developed using the interactive MATLAB (MATrix Laboratory) App Designer environment. We aim to provide a user-friendly tool as a learning aid system for students to gain a comprehensive understanding of the subject as well as for teaching.
Enhancing learning of the Grad-Shafranov equation through scientific literature: part 2 of a physics education series
(Sociedade Brasileira de Física) Santos, Lenadro Nunes dos; Ojeda González, Arian; La Luz, Victor Hugo de; Oliveira, Virgínia Klausner de; Pilling, Sergio; Prestes, Alan; Sousa, Antonio Nilson Laurindo; Oliveira, Matheus Felipe Cristaldo de
In part 1 of our physics education series, we introduced a novel solution based on Yoon-Lui’s solutions 1 and 2. Building upon that, this follow-up presents a new solution obtained by combining the generating functions of Yoon-Lui-1 and Yoon-Lui-3, resulting in a new and simplified general solution. We also calculate the singular points and determine their coordinates for various parameter values. A graphical representation of the solution is presented, showing the magnetic field lines and current density distribution. The behavior of the magnetic field and the effect of varying the parameter are discussed. The observed magnetic islands and singular points are relevant in the fields of Plasma Physics and Space Physics, providing insights into magnetic structures in plasmas and their impact on confinement and stability. Furthermore, this study encourages innovation and equips researchers and students with the necessary tools to make meaningful contributions to the field, emphasizing the integration of scientific literature into physics education to promote a comprehensive understanding of physical concepts and their practical applications.
Chemical Evolution of CO2 Ices under Processing by Ionizing Radiation: Characterization of Nonobserved Species and Chemical Equilibrium Phase with the Employment of PROCODA Code
(IOP science) Pilling, Sergio; Carvalho, Geanderson Araújo; Rocha, Will Robson Monteiro
Astrophysical ices are being exposed to ionizing radiation in space environments, which trigger new reactions and desorption processes. In the lab, such processing by radiation has revealed the appearance of several new species and complements the study of the chemical evolution of icy astrophysical scenarios. Here, we develop a computational methodology that helps to clarify the chemical evolution of ices investigated experimentally under photolysis/radiolysis processes until reaching chemical equilibrium (CE). Briefly, the code (named PROCODA) solves a system of coupled differential equations and describes the evolution of the molecular abundances with the irradiation time for ices under processing by radiation. Two experimental ice samples containing pure CO2 and irradiated by two ionizing agents (cosmic rays and ultraviolet photons) were considered prototype systems. Here, we considered 11 different chemical species within the ice (four observed: CO2, CO, O3, and CO3; seven nonobserved or unknown: O, O2, C, C2, C2O, C2O2, and C2O3), 100 reaction routes (e.g., direct dissociation reactions, bimolecular and termolecular reactions) and radiation-induced desorption processes. The best-fit models provide the reaction rates, several desorption parameters, as well as the characterization of the CE phase. At CE, the percentage of nonobserved species in the UV model was almost triple the one calculated in the CR model (which also includes a lot of O and C atoms). The determined values can be employed in future astrochemical models to map chemical evolution embedded species in astrophysical regions under the presence of an ionizing radiation field.
Analysis of Y-component of geomagnetic field and SYM-H Index using wavelet multiresolution analysis
(Springer Nature Link) Sapkota, Santosh; Saurav, Sarup Khadka; Gautam, Sabin; Karki, Monika; Adhikari, Binod; Mishra, Roshan Kumar; Oliveira, Virgínia Klausner de; Dhungana, Beni Madhav
Electrodynamical coupling between the solar wind’s plasma and the Earth’s magnetosphere cre- ates geomagnetic disturbances recorded on the ground. This work analyzes the Y-component of the geomag- netic field during two geomagnetic storms and compares it to the solar quiet days. The magnetogram data recorded on low latitude stations are used for the study. We investigated the correlation of the Y-component with geomagnetic index SYM-H using wavelet multiresolution analysis. We have used solar wind velocity, pressure, and interplanetary magnetic fields (By and Bz) to know the interplanetary structure for the selected duration. We found a positive correlation between Y-component and the SYM-H index for both events. The magnitude of the Y-component was significantly reduced during the main phase in comparison to the quiet days. Further, variation of solar wind parameters indicated geomagnetic storms are guided by the prolonged southward IMF-Bz component and highly fluctuated IMF-By component. This work connects the inter- planetary plasma parameters to the storm-time geomagnetic variations.
Climatology of ionospheric amplitude scintillation on GNSS signals at south American sector during solar cycle 24
(Elsevier) Macho, Eduardo Perez; Correia, Emília; Spogli, Luca; Muella, Marcio Tadeu de Assis Honorato
Scintillations are caused by ionospheric irregularities and can affect the propagation of trans-ionospheric radio signals. One way to understand and predict the impact of such irregularities on Global Navigation Satellite System (GNSS) signals is through the spatial/temporal characterization of the scintillation’s climatology during different phases of a solar cycle covering different latitudes and longitudes. This characterization is performed using amplitude scintillation index S4, during the full solar cycle 24, in the South American (SA) sector. The investigation considers the diurnal, daily, and seasonal variation of S4 index for climatological purpose, and the goal of this study is to investigate the scintillations covering a large spatial scale during the full solar cycle 24. The characterization shows a latitudinal asymmetry, whereas at the south, the scintillations were more frequent and their peak was more distant from the magnetic equator, which can be attributed by the South Atlantic Magnetic Anomaly (SAMA), and/or by the transequatorial meridional neutral winds. It also shows a longitudinal asymmetry, where the scintillations at the eastern sector occurred between November and February, while at the western sector, they occurred during the months of October, November, February and March, which can be attributed to the difference between the magnetic and geographic equators. The occurrence of scintillations during two distinct geomagnetic storms with similar storm time in the SA sector is also presented.
Glycolaldehyde formation mediated by interstellar amorphous ice: a computational study
(Royal Astronomical Society) Paiva, Mateus Augusto Martins; Pilling, Sergio; Mendoza, Edgar; Galvão, Breno Rodrigues Lamaghere; Abreu, Heitor Avelino de
Glycolaldehyde (HOCH2CHO) is the most straightforward sugar detected in the Interstellar Medium (ISM) and participates in the formation pathways of molecules fundamental to life, red such as ribose and derivatives. Although detected in several regions of the ISM, its formation route is still debated and its abundance cannot be explained only by reactions in the gas phase. This work explores a new gas-phase formation mechanism for glycolaldehyde and compares the energy barrier reduction when the same route happens on the surface of amorphous ices. The first step of the mechanism involves the formation of a carbon–carbon bond between formaldehyde (H2CO) and the formyl radical (HCO), with an energy barrier of 27 kJ mol−1 (gas-phase). The second step consists of barrierless hydrogen addition. Density functional calculations under periodic boundary conditions were applied to study this reaction path on 10 different amorphous ice surfaces through an Eley–Rideal type mechanism. It was found that the energy barrier is reduced on average by 49 per cent, leading in some cases to a 100 per cent reduction. The calculated adsorption energy of glycolaldehyde suggests that it can be promptly desorbed to the gas phase after its formation. This work, thus contributes to explaining the detected relative abundances of glycolaldehyde and opens a new methodological framework for studying the formation routes for Complex Organic Molecules (COMs) in interstellar icy grains.

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