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Absence of High Frequency Echoes From Ionosondes During the 23–25 April 2023 Geomagnetic Storm; What Happened?
(Advancing Earth and Space Sciences) Habarulema, John Bosco; Zhang, Yongliang; Matamba, Tshimangadzo; Lu, Gang; Katamzi‐Joseph, Zama; Fagundes, Paulo Roberto; Okoh, Daniel; Seemala, Gopi
We report an unusual event on absence of high frequency (HF) echoes in ionosonde observations from the ionospheric F2 region during the geomagnetic storm of 23–25 April 2023. This event was observed in both southern and northern hemispheres over two stations, Grahamstown (33.3°S, 26.5°E), South Africa and Pruhonice (50.0°N, 14.6°E), Czech Republic. Significant O/N2 depletion over the stations was observed by TIMED/GUVI, indicating a strong negative ionospheric storm. This is unique since absence of echoes in ionosonde measurements is usually due to strong radio absorption in the ionosphere associated with solar flares. However, there was no flare activity during the periods of “absent” F2 HF echoes. On the other hand, the ionosonde detected echoes from E‐layer. TIEGCM simulation reproduced TIMED/GUVI O/N2 depletion and showed that NmE was larger than NmF2 on dayside over Pruhonice. TIMED/GUVI O/N2 also showed a clear spatial gradient in the O/N2 depleted regions, suggesting F‐region ionosphere was tilted. By estimating the critical frequency of the F2 layer using GNSS observations, we have shown that it wasn't possible for the ionospheric electron density to reach depletion levels prohibiting reflection of HF echoes from ionosondes. We suggest that this phenomena may have been caused by either (a) maximum electron density of E layer exceeding that of F2 layer and/or (b) ionospheric tilting which made the signals to be reflected far away from the ionosonde locations.
AGN feedback and star formation in the peculiar galaxy NGC 232: insights from VLT-MUSE observations
(Royal Astronomical Society) Souza, José Henrique Costa; Riffel, Rogemar André; Dors Junior, Oli Luiz; Riffel, Rogério; Poppe, Paulo César da Rocha
We use VLT-MUSE integral field unit data to study the ionized gas physical properties and kinematics as well as the stellar populations of the Seyfert 2 galaxy NGC 232 as an opportunity to understand the role of AGN feedback on star formation. The data cover a field of view of 60 × 60 arcsec2 at a spatial resolution of ∼850 pc. The emission-line profiles have been fitted with two Gaussian components, one associated to the emission of the gas in the disc and the other due to a bi-conical outflow. The spectral synthesis suggests a predominantly old stellar population with ages exceeding 2 Gyr, with the largest contributions seen at the nucleus and decreasing outwards. Meanwhile, the young and intermediate age stellar populations exhibit a positive gradient with increasing radius and a circum-nuclear star-forming ring with radius of ∼0.5 kpc traced by stars younger than 20 Myr, is observed. This, along with the fact that AGN and SF dominated regions present similar gaseous oxygen abundances, suggests a shared reservoir feeding both star formation and the AGN. We have estimated a maximum outflow rate in ionized gas of ∼1.26 M yr−1 observed at a distance of ∼560 pc from the nucleus. The corresponding maximum kinetic power of the outflow is ∼3.4 × 1041 erg s−1. This released energy could be sufficient to suppress star formation within the ionization cone, as evidenced by the lower star formation rates observed in this region.
Ahead-of-Tsunami magnetic disturbance detection using intrinsic mode functions: Tohoku-Oki earthquake case study
(Springer Nature Link) Oliveira, Virgínia Klausner de; Macedo, Humberto Gimenes; Prestes, Alan
We document magnetic disturbances that occurred during the Tohoku-Oki tsunami of 11 March 2011 using empirical mode decomposition (EMD) in a dataset derived from a network of ground-based magnetometers (INTERMAGNET and GIS). The disturbances, obtained by filtering the magnetic field data using the first intrinsic mode function (IMF1) of EMD, propagate ahead of the tsunami at a speed in the range of 600–1.6 km/s. They also appear 3 min (near-field) to 2 h (far-field) earlier than the tsunami arrival at the magnetic observatories. We refer to these distur- bances as ahead-of-tsunami magnetic disturbances (ATMDs). A comparison with seismometer data shows them arriving 10 min after the arrival of Rayleigh waves. Their association with both seismogenic and tsunamigenic processes is discussed, and it is argued that the tsunamigenic process can well explain the magnetic disturbance propagation characteristics at the far-field. At near- field, the ATMDs are the coseismic magnetic signatures mainly driven by surface Rayleigh waves. Monitoring these ATMDs can be extremely useful for the early warning of the tsunami.
Análise de componentes principais aplicada à dendrocronologia
Silva, Daniela Oliveira da; Oliveira, Virgínia Klausner de; Prestes, Alan; Macedo, Humberto Gimenes
Analysis of Y-component of geomagnetic field and SYM-H Index using wavelet multiresolution analysis
(Springer Nature Link) Sapkota, Santosh; Saurav, Sarup Khadka; Gautam, Sabin; Karki, Monika; Adhikari, Binod; Mishra, Roshan Kumar; Oliveira, Virgínia Klausner de; Dhungana, Beni Madhav
Electrodynamical coupling between the solar wind’s plasma and the Earth’s magnetosphere cre- ates geomagnetic disturbances recorded on the ground. This work analyzes the Y-component of the geomag- netic field during two geomagnetic storms and compares it to the solar quiet days. The magnetogram data recorded on low latitude stations are used for the study. We investigated the correlation of the Y-component with geomagnetic index SYM-H using wavelet multiresolution analysis. We have used solar wind velocity, pressure, and interplanetary magnetic fields (By and Bz) to know the interplanetary structure for the selected duration. We found a positive correlation between Y-component and the SYM-H index for both events. The magnitude of the Y-component was significantly reduced during the main phase in comparison to the quiet days. Further, variation of solar wind parameters indicated geomagnetic storms are guided by the prolonged southward IMF-Bz component and highly fluctuated IMF-By component. This work connects the inter- planetary plasma parameters to the storm-time geomagnetic variations.
Assessing the effects of a minor CIR‐HSS geomagnetic storm on the brazilian low‐latitude ionosphere: ground and space‐based observations
(Advancing Earth and Space Sciences) Chingarandi, Frank Simbarashe; Cândido, Claudia Maria Nicoli; Guedes, Fabio Becker; Jonah, Olusegun Folarin; Santos, Stella Pires Moraes; Klausner, Virgínia; Osanyin, Taiwo Olusayo
This paper investigates the effects of a minor G1 Co-rotating Interaction Region (CIR)/High-Speed Stream (HSS)-driven geomagnetic storm that occurred on (13–14 October 2018), during deep solar minimum. We used simultaneous observations from multiple instruments, namely; ground-based Global Navigation Satellite Systems (GNSS) receivers, a Digisonde, ground magnetometers, and space-based observations from the National Aeronautics and Space Administration Global-scale Observations of Limb and Disk (GOLD) and SWARM missions. This study presents a detailed picture of the low-latitude ionosphere response over the Brazilian sector during a minor storm. Our results showed that the minor CIR/HSS-driven storm caused a positive ionospheric storm of over ∼20 TECU in magnitude. For the first time, periodic post-sunset irregularities and Equatorial Plasma Bubbles, equatorial plasma bubbles, were analyzed using GOLD FUV OI 135.6 nm emission, Total Electron Content (TEC) maps, Rate of TEC index, ROTI, and TEC gradients. Fluctuations in the interplanetary magnetic field Bz and changes in the thermospheric column density ratio (∑O/N2) are discussed as the main sources of ionospheric changes during the storm. This paper highlights the importance of monitoring and understanding the impact of Sun-Earth interactions and provides insight into the behavior of the low-latitude ionosphere during minor geomagnetic storms.
Breaking the Degeneracy in Magnetic Cataclysmic Variable X-Ray Spectral Modeling Using X-Ray Light Curves
(IOP science) Belloni, Diogo; Rodrigues, Claudia Vilega; Schreiber, Matthias R.; Castro, Manuel; Costa, Joaquim Eduardo Rezende; Hayashi, Takayuki; Lima, Isabel de Jesus; Luna, Gerardo Juan Manuel; Martins, Murilo; Oliveira, Alexandre Soares de; Parsons, Steven G.; Silva, Karleyne Medeiros Gomes da; Stecchini, Paulo Eduardo; Stuchi, Teresa de Jesus; Zorotovic, Monica
We present an analysis of mock X-ray spectra and light curves of magnetic cataclysmic variables using an upgraded version of the 3D cyclops code. This 3D representation of the accretion flow allows us to properly model total and partial occultation of the postshock region by the white dwarf as well as the modulation of the X-ray light curves due to the phase-dependent extinction of the preshock region. We carried out detailed postshock region modeling in a four-dimensional parameter space by varying the white dwarf mass and magnetic field strength as well as the magnetosphere radius and the specific accretion rate. To calculate the postshock region temperature and density profiles, we assumed equipartition between ions and electrons; took into account the white dwarf gravitational potential, the finite size of the magnetosphere, and a dipole-like magnetic field geometry; and considered cooling by both bremsstrahlung and cyclotron radiative processes. By investigating the impact of the parameters on the resulting X-ray continuum spectra, we show that there is an inevitable degeneracy in the four-dimensional parameter space investigated here, which compromises X-ray continuum spectral fitting strategies and can lead to incorrect parameter estimates. However, the inclusion of X-ray light curves in different energy ranges can break this degeneracy, and it therefore remains, in principle, possible to use X-ray data to derive fundamental parameters of magnetic cataclysmic variables, which represents an essential step toward understanding their formation and evolution.
Calibration-based abundances in the interstellar gas of galaxies from slit and IFU spectra
(EDP Sciences) Pilyugin, Leonid; Lara-López, Maritza A.; Vílchez, Jose M.; Duarte Puertas, Salvador; Zinchenko, Igor; Dors Junior, Oli Luiz
In this work, we make use of available integral field unit (IFU) spectroscopy and slit spectra of several nearby galaxies. The pre- existing empirical R and S calibrations for abundance determinations are constructed using a sample of H ii regions with high- quality slit spectra. In this paper, we test the applicability of those calibrations to the IFU spectra. We estimate the calibration-based abundances obtained using both the IFU and the slit spectroscopy for eight nearby galaxies. The median values of the slit and IFU spectra-based abundances in bins of 0.1 in fractional radius Rg (normalised to the optical radius R25) of a galaxy are determined and compared. We find that the IFU and the slit spectra-based abundances obtained through the R calibration are close to each other; the mean value of the differences of abundances is 0.005 dex, and the scatter in the differences is 0.037 dex for 38 datapoints. The S calibration can produce systematically underestimated values of the IFU spectra-based abundances at high metallicities (12 + log(O/H) 􏰅8.55); the mean value of the differences is −0.059 dex for 21 datapoints, while at lower metallicities the mean value of the differences is −0.018 dex and the scatter is 0.045 dex for 36 data points. This provides evidence that the R calibration produces more consistent abundance estimations between the slit and the IFU spectra than the S calibration. We find that the same calibration can produce close estimations of the abundances using IFU spectra obtained with different spatial resolution and different spatial samplings. This is in line with the recent finding that the contribution of the diffuse ionised gas to the large-aperture spectra of H ii regions has a secondary effect.
Characterization of acetonitrile ice irradiated by X-rays employing the procoda code – II. Desorption processes
(Royal Astronomical Society) Carvalho, Geanderson Araújo; Pilling, Sergio; Gerasimenko, Svitlana
In this work, we focus on the study of radiation-induced desorption processes that occurred in acetonitrile ice irradiated by broad-band X-rays (6 eV to 2 keV) monitored by Fourier transform infrared spectroscopy at different radiation fluences. In a previous work, we used the procoda code to derive the chemical evolution of the ice. Here, we have observed that the acetonitrile desorbed column density is at least two orders of magnitude larger than the desorbed column densities of daughter or granddaughter molecular species at chemical equilibrium stage. This indicates that total desorption column density is mainly governed by the father molecule, as also previously hypothesized in experimental studies. This occurs basically because the acetonitrile column density is larger than the other ones. In particular, at chemical equilibrium acetonitrile desorption column density represents almost 98 per cent of the total, while it is close to 1 per cent for H, CN, and CH2, the species with larger molecular desorption percentages at chemical equilibrium. Another derived quantity is what we called intrinsic desorption rate, which is a number per second for individual species. Some of the larger intrinsic desorption rates were 6.2 × 10−6 (CH3CN), 6.2 × 10−6 (CN), 5.7 × 10−6 (H), 5.7 × 10−6 (CH2), and 4.4 × 10−6 (C2N2). These results help to put constraints in astrochemical models and can also be useful to clarify some astronomical radio observations.
Chemical abundance of LINER galaxies – metallicity calibrations based on SDSS-IV MaNGA
(Royal Astronomical Society) Oliveira Junior, Celso Benedito de; Krabbe, Angela Cristina; Hernandez-Jimenez, Jose Andres; Dors Junior, Oli Luiz; Zinchenko, Igor; Hägele, Guilhermo Frederico; Cardaci, Mónica Viviana; Monteiro, Adriano Francisco
The ionizing source of low-ionization nuclear emission-line regions (LINERs) is uncertain. Because of this, an empirical relation to determine the chemical abundances of these objects has not been proposed. In this work, for the first time, we derived two semi-empirical calibrations based on photoionization models to estimate the oxygen abundance of LINERS as a function of the N2 and O3N2 emission-line intensity ratios. These relations were calibrated using oxygen abundance estimations obtained by comparing the observational emission-line ratios of 43 LINER galaxies (taken from the MaNGA survey) and grids of photoionization models built with the cloudy code assuming post-asymptotic giant branch stars with different temperatures. We found that the oxygen abundance of LINERs in our sample is in the range, with a mean value of . We recommend the use of the N2 index to estimate the oxygen abundances of LINERs, since the calibration with this index presented a much smaller dispersion than the O3N2 index. In addition, the estimated metallicities are in good agreement with those derived by extrapolating the disc oxygen abundance gradients to the centre of the galaxies showing that the assumptions of the models are suitable for LINERs. We also obtained a calibration between the logarithm of the ionization parameter and the [O iii]/[O ii] emission-line ratio.
Chemical abundance of the LINER galaxy UGC 4805 with SDSS-IV MaNGA
(Royal Astronomical Society) Krabbe, Angela Cristina; Oliveira Junior, Celso Benedito de; Zinchenko, Igor A.; Hernández-Jiménez, Jose Andres; Dors Júnior, Oli Luiz; Hägele, Guilhermo Frederico; Cardaci, Mónica Viviana; Telles, Nayra Regina
Chemical abundance determinations in Low-Ionization Nuclear Emission-line Regions (LINERs) are especially complex and uncertain because the nature of the ionizing source of this kind of object is unknown. In this work, we study the oxygen abundance in relation to the hydrogen abundance (O/H) of the gas phase of the UGC 4805 LINER nucleus. Optical spectroscopic data from the Mapping Nearby Galaxies survey was employed to derive the O/H abundance of the UGC 4805 nucleus based on the extrapolation of the disc abundance gradient, on calibrations between O/H abundance and strong emission-lines for active galactic nuclei (AGNs) as well as on photoionization models built with the Cloudy code, assuming gas accretion into a black hole (AGN) and post-asymptotic giant branch (p-AGB) stars with different effective temperatures. We found that abundance gradient extrapolations, AGN calibrations, AGN, and p-AGB photoionization models produce similar O/H values for the UGC 4805 nucleus and similar ionization parameter values. The study demonstrated that the methods used to estimate the O/H abundance using nuclear emission-line ratios produce reliable results, which are in agreement with the O/H values obtained from the independent method of galactic metallicity gradient extrapolation. Finally, the results from the WHAN diagram combined with the fact that the high excitation level of the gas has to be maintained at kpc scales, we suggest that the main ionizing source of the UGC 4805 nucleus probably has a stellar origin rather than an AGN.
Chemical abundances in Seyfert galaxies – IX. Helium abundance estimates
(Royal Astronomical Society) Dors Junior, Oli Luiz; Valerdi, Mabel; Lemes, Priscila Freitas; Krabbe, Angela Cristina; Riffel, Rogemar André; Amôres, Eduardo Brescansin; Riffel, Rogério; Armah, Mark; Monteiro, Adriano Francisco; Oliveira Junior, Celso Benedito de
For the first time, the helium abundance relative to hydrogen (He/H), which relied on direct measurements of the electron temperature, has been derived in the narrow line regions (NLRs) from a local sample of Seyfert 2 nuclei. In view of this, optical emission line intensities [3000 < λ(Å) < 7000] of 65 local Seyfert 2 nuclei (z < 0.2), taken from Sloan Digital Sky Survey Data Release 15 and additional compilation from the literature, were considered. We used photoionization model grid to derive an Ionization Correction Factor (ICF) for the neutral helium. The application of this ICF indicates that the NLRs of Seyfert 2 present a neutral helium fraction of ∼50 per cent in relation to the total helium abundance. We find that Seyfert 2 nuclei present helium abundance ranging from 0.60 to 2.50 times the solar value, while ∼85 per cent of the sample present oversolar abundance values. The derived (He/H)–(O/H) abundance relation from the Seyfert 2 is stepper than that of star-forming regions (SFs) and this difference could be due to excess of helium injected into the interstellar medium by the winds of Wolf–Rayet stars. From a regression to zero metallicity, by using Seyfert 2 estimates combined with SFs estimates, we obtained a primordial helium mass fraction Yp = 0.2441 ± 0.0037, a value in good agreement with the one inferred from the temperature fluctuations of the cosmic microwave background by the Planck Collaboration
Chemical abundances in Seyfert galaxies – V. The discovery of shocked emission outside the AGN ionization axis
(Royal Astronomical Society) Riffel, Rogemar André; Dors Júnior, Oli Luiz; Armah, Mark; Bergmann, Thaisa Storchi; Feltre, Anna; Hägele, Guilhermo Frederico; Cardaci, Mónica Viviana; Dutra, Daniel Ruschel; Krabbe, Angela Cristina; Pérez-Montero, Enrique; Zakamska, Nadia L.; Freitas, Izabel C.
We present maps for the electron temperature in the inner kpc of three luminous Seyfert galaxies: Mrk 79, Mrk 348, and Mrk 607 obtained from Gemini Multi-Object Spectrograph-integral field unit observations at spatial resolutions of ∼110–280 pc. We study the distributions of electron temperature in active galaxies and find temperatures varying in the range from ∼8000 to > 30000 K. Shocks due to gas outflows play an important role in the observed temperature distributions of Mrk 79 and Mrk 348, while standard photoionization models reproduce the derived temperature values for Mrk 607. In Mrk 79 and Mrk 348, we find direct evidence for shock ionization with overall orientation orthogonal to the ionization axis, where shocks can be easily observed as the active galactic nuclei radiation field is shielded by the nuclear dusty torus. This also indicates that even when the ionization cones are narrow, the shocks can be much wider angle.
Chemical abundances in Seyfert galaxies – VI. Empirical abundance calibration
(Royal Astronomical Society) Dors Júnior, Oli Luiz
We derived a bi-dimensional calibration between the emission-line ratios R23 =([OII]λ3726+λ3729+[OIII]λ4959+ λ5007)/H β , P = [([O III] λ4959 + λ5007)/H β ]/R23 and the oxygen abundance relative to hydrogen (O/H) in the gas phase of Seyfert 1 and 2 nuclei. In view of this, emission-line intensity ratios for a sample of objects taken from the Sloan Digital Sky Survey Data Release 7 measured by the MPA/JHU group and direct estimates of O/H based on Te-method, adapted for active galactic nuclei (AGNs), are considered. We find no variation of R23 observed along the radii of AGNs, which shows that this line ratio is a good oxygen abundance (O/H) indicator for the class of objects considered in this work. The derived O/H = f(R23, P) relation produces O/H values similar to estimations via Te-method in a wide range of metallicities [8.0 < 12 + log (O/H) < 9.2]. Conversely to star-forming regions in the high-metallicity regime, R23 shows a positive correlation trend with O/H in AGNs. This indicates that the hardness of ionizing radiation is not affected by the metallicities in these objects or narrow-line regions are not significantly modified by changes in the spectral energy distribution due to metallicity variations.
Chemical abundances in Seyfert galaxies – VII. Direct abundance determination of neon based on optical and infrared emission lines
(Royal Astronomical Society) Armah, Mark; Dors Júnior, Oli Luiz; Aydar, Catarina Pasta; Cardaci, Mónica Viviana; Hägele, Guilhermo Frederico; Feltre, Anna; Riffel, Rogério; Riffel, Rogemar André; Krabbe, Angela Cristina
For the first time, neon abundance has been derived in the narrow line region from a sample of Seyfert 2 nuclei. In view of this, we compiled from the literature fluxes of optical and infrared (IR) narrow emission lines for 35 Seyfert 2 nuclei in the local universe (z 0.06). The relative intensities of emission lines were used to derive the ionic and total neon and oxygen abundances through electron temperature estimations (Te-method). For the neon, abundance estimates were obtained by using both Te-method and IR-method. Based on photoionization model results, we found a lower electron temperature [te(Ne iii)] for the gas phase where the Ne2 + is located in comparison with t3 for the O2 + ion. We find that the differences (D) between Ne2 +/H+ ionic abundances calculated from IR-method and Te-method (assuming t3 in the Ne2 +/H+ derivation) are similar to the derivations in star-forming regions (SFs) and they are reduced by a mean factor of ∼3 when te(Ne iii) is considered. We propose a semi-empirical Ionization Correction Factor (ICF) for the neon, based on [Ne II]12.81μm, [Ne III]15.56μm, and oxygen ionic abundance ratios. We find that the average Ne/H abundance for the Seyfert 2s sample is nearly 2 times higher than similar estimate for SFs. Finally, for the very high metallicity regime (i.e. [12 + log(O/H) 8.80]) an increase in Ne/O with O/H is found, which likely indicates secondary stellar production for the neon.
Chemical abundances in Seyfert galaxies – VIII. Argon abundance estimates
(Royal Astronomical Society) Monteiro, Adriano Francisco; Dors Júnior, Oli Luiz
For the first time, the argon abundance relative to hydrogen abundance (Ar/H) in the narrow line region of a sample of Seyfert 2 nuclei has been derived. In view of this, optical narrow emission line intensities of a sample of 64 local Seyfert 2 nuclei (z < 0.25) taken from Sloan Digital Sky Survey DR7 and measured by the MPA/JHU group were considered. We adopted the Te-method for AGNs, which is based on direct determination of the electron temperature, together with a grid of photoionization model results, built with the CLOUDY code, to obtain a method for the derivation of the Ar/H abundance. We find that for a metallicity range of 0.2 (Z/Z) 2.0, Seyfert 2 nuclei present Ar/H abundance ranging from ∼0.1 to ∼3 times the argon solar value, adopting log(O/H) = −3.31 and log(Ar/H) = −5.60. These range of values correspond to 8.0 (12 + log(O/H) 9.0 and 5.4 (12 + log(Ar/H) 6.9, respectively. The range of Ar/H and Ar/O abundance values obtained from our sample are in consonance with estimations from extrapolations of the radial abundance gradients to the central parts of the disc for four spiral galaxies. We combined our abundance results with estimates obtained from a sample of H II galaxies, which were taken from the literature, and found that the Ar/O abundance ratio decreases slightly as the O/H abundance increases.
Chemical abundances in Seyfert galaxies – X. Sulphur abundance estimates
(Royal Astronomical Society) Dors Junior, Oli Luiz; Valerdi, Mabel; Riffel, Rogemar André; Riffel, Rogério; Cardaci, Mónica Viviana; Hägele, Guilhermo Frederico; Armah, Mark; Revalski, Mitchell; Flury, Sophia; Lemes, Priscila Freitas; Amôres, Eduardo; Krabbe, Angela Cristina; Binette, Luc; Feltre, Anna; Bergmann, Thaisa Storchi
For the first time, the sulphur abundance relative to hydrogen (S/H) in the narrow-line regions of a sample of Seyfert 2 nuclei (Sy 2s) has been derived via direct estimation of the electron temperature. Narrow emission-line intensities from the Sloan Digital Sky Survey (SDSS) Data Release 17 (DR17) [in the wavelength range 3000 < λ(Å) < 9100] and from the literature for a sample of 45 nearby (z < 0.08) Sy 2s were considered. Our direct estimates indicate that Sy 2s have similar temperatures in the gas region where most of the S+ ions are located in comparison with that of star-forming regions (SFs). However, Sy 2s present higher temperature values (∼10 000 K) in the region where most of the S2+ ions are located relative to that of SFs. We derive the total sulphur abundance in the range of 6.2 􏰀 12 + log(S/H) 􏰀 7.5, corresponding to 0.1–1.8 times the solar value. These sulphur abundance values are lower by ∼0.4 dex than those derived in SFs with similar metallicity, indicating a distinct chemical enrichment of the interstellar medium (ISM) for these object classes. The sulphur abundance relative to oxygen (S/O) values for our Sy 2 sample present an abrupt (∼0.5 dex) decrease with increasing oxygen abundance relative to hydrogen (O/H) for the high-metallicity regime [12 + log(O/H) 􏰁 8.7)], what is not seen for the SFs. However, when our Sy 2 estimates are combined with those from a large sample of SFs, we did not find any dependence between S/O and O/H.
Chemical abundances of LINER galaxies – nitrogen abundance estimations
(Royal Astronomical Society) Oliveira Junior, Celso Benedito de ; Krabbe, Angela Cristina; Dors Junior, Oli Luiz; Zinchenko, Igor; Hernandez-Jimenez, José Andrés; Cardaci, Mónica Viviana; Hägele, Guilhermo Frederico; Ilha, Gabriele da Silva
In this work, we investigated the nitrogen and oxygen abundances in a sample of galaxies with Low Ionization Nuclear Emission Regions (LINERs) in their nucleus. Optical spectroscopic data (3600 – 10 000 Å) of 40 LINERs from the Mapping Nearby Galaxies (MaNGAs) survey were considered. Only objects classified as retired galaxies, that is, whose main ionization sources are post-Asymptotic Giant Branch (pAGB) stars, were selected. The abundance estimates were obtained through detailed photoionization models built with the CLOUDY code to reproduce a set of observational emission line intensities ratios of the sample. Our results show that LINERs have oxygen and nitrogen abundances in the ranges of 8.0 􏰀 12 + log(O/H) 􏰀 9.0 (mean value 8.74 ± 0.27) and 7.6 􏰀 12 + log(N/H) 􏰀 8.5 (mean value 8.05 ± 0.25), respectively. About 70 per cent of the sample have oversolar O/H and N/H abundances. Our abundance estimates are in consonance with those for Seyfert 2 nuclei and H II regions with the highest metallicity, indicating that these distinct object classes show similar enrichment of the interstellar medium (ISM). The LINERs in our sample are located in the higher N/O region of the N/O versus O/H diagram, showing an unexpected negative correlation between these two parameters. These results suggest that these LINERs mainly exhibit a secondary nitrogen production and could be acting some other mechanisms that deviate them from the usual theoretical secondary nitrogen production curve and the H II regions observations. However, we did not find any evidence in our data able to support the literature suggested mechanisms. Alternatively, our results show that LINERs do not present any correlation between the N/O abundances and the stellar masses of the hosting galaxies.
Chemical changes induced during heating of acetonitrile-rich ice pre-irradiated by X-rays and its implication in astrochemistry
(Elsevier) Carvalho, Geanderson Araújo; Pilling, Sergio
In this work, we investigate the effects induced by the heating of acetonitrile-rich ice from 13 K to 350 K. Before the heating, the sample was irradiated at 13 K by broadband X-rays (6 eV to 2 keV), which trigger the production of new molecules, such as HCN, H2CCNH, CH4 and CH3NC (see Carvalho and Pilling, 2020) and also induced desorption of frozen species to gas-phase. New spectra were collected during heating to investigate whether new species, not present before at lower temperatures, appear due to thermal processing. New infrared bands were identified at temperatures around 120 K and 300 K, from which it was possible to notice the possible presence of HCN/CN radical, ammonia and C2N2. It was also verified that acetonitrile has a thermal desorption peak between 120 K and 200 K, which yields to the vanishing of acetonitrile within the sample for temperatures of 200 K and above. Some infrared features assigned before solely to acetonitrile remain for sample temperatures > 200 K, which indicates the presence of blended species with similar infrared features. From analyzing those blended peaks, we also perceived the possible presence of aminoacetonitrile.
Chemical Evolution of CO2 Ices under Processing by Ionizing Radiation: Characterization of Nonobserved Species and Chemical Equilibrium Phase with the Employment of PROCODA Code
(IOP science) Pilling, Sergio; Carvalho, Geanderson Araújo; Rocha, Will Robson Monteiro
Astrophysical ices are being exposed to ionizing radiation in space environments, which trigger new reactions and desorption processes. In the lab, such processing by radiation has revealed the appearance of several new species and complements the study of the chemical evolution of icy astrophysical scenarios. Here, we develop a computational methodology that helps to clarify the chemical evolution of ices investigated experimentally under photolysis/radiolysis processes until reaching chemical equilibrium (CE). Briefly, the code (named PROCODA) solves a system of coupled differential equations and describes the evolution of the molecular abundances with the irradiation time for ices under processing by radiation. Two experimental ice samples containing pure CO2 and irradiated by two ionizing agents (cosmic rays and ultraviolet photons) were considered prototype systems. Here, we considered 11 different chemical species within the ice (four observed: CO2, CO, O3, and CO3; seven nonobserved or unknown: O, O2, C, C2, C2O, C2O2, and C2O3), 100 reaction routes (e.g., direct dissociation reactions, bimolecular and termolecular reactions) and radiation-induced desorption processes. The best-fit models provide the reaction rates, several desorption parameters, as well as the characterization of the CE phase. At CE, the percentage of nonobserved species in the UV model was almost triple the one calculated in the CR model (which also includes a lot of O and C atoms). The determined values can be employed in future astrochemical models to map chemical evolution embedded species in astrophysical regions under the presence of an ionizing radiation field.

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